Solid-State Metal Additive Manufacturing
Timely summary of state-of-the-art solid-state metal 3D printing technologies, focusing on fundamental processing science and industrial applications
Solid-State Metal Additive Manufacturing: Physics, Processes, Mechanical Properties, and Applications provides detailed and in-depth discussion on different solid-state metal additive manufacturing processes and applications, presenting associated methods, mechanisms and models, and unique benefits, as well as a detailed comparison to traditional fusion-based metal additive manufacturing.
The text begins with a high-level overview of solid-state metal additive manufacturing with an emphasis on its position within the metal additive manufacturing spectrum and its potential for meeting specific demands in the aerospace, automotive, and defense industries. Next, each of the four categories of solid-state additive technologies—cold spray additive manufacturing, additive friction stir deposition, ultrasonic additive manufacturing, and sintering-based processes—is discussed in depth, reviewing advances in processing science, metallurgical science, and innovative applications. Finally, the future directions of these solid-state processes, especially the material innovation and artificial intelligence aspects, are discussed.
Sample topics covered in Solid-State Metal Additive Manufacturing include:
Physical processes and bonding mechanisms in impact-induced bonding and microstructures and microstructural evolution in cold sprayed materials Process fundamentals, dynamic microstructure evolution, and potential industrial applications of additive friction stir deposition Microstructural and mechanical characterization and industrial applications of ultrasonic additive manufacturing Principles of solid-state sintering, binder jetting-based metal printing, and sintering-based metal additive manufacturing methods for magnetic materials Critical issues inherent to melting and solidification, such as porosity, high residual stress, cast microstructure, anisotropic mechanical properties, and hot cracking
Solid-State Metal Additive Manufacturing is an essential reference on the subject for academic researchers in materials science, mechanical, and biomedicine, as well as professional engineers in various manufacturing industries, especially those involved in building new additive technologies.
Preface xiii Part I Introduction 1 1 Introduction and Overview 3 Hang Z. Yu, Nihan Tuncer, and Zhili Feng 1.1 Overview and History of Metal Additive Manufacturing 4 1.2 Liquid-State Bonding Versus Solid-State Bonding 7 1.2.1 Liquid-State Bonding 7 1.2.2 Solid-State Bonding 8 1.3 Nonbeam-Based, Solid-State Metal Additive Manufacturing 9 1.3.1 Deformation-Based Metal Additive Manufacturing 9 1.3.2 Sintering-Based Metal Additive Manufacturing 11 1.4 Additive Manufacturing Categorization Based on the Relationship Between Shape Forming and Consolidation 12 1.5 Organization of the Book 14 References 15 Part II Cold Spray Additive Manufacturing 19 2 Impact-Induced Bonding: Physical Processes and Bonding Mechanisms 21 David Veysset and Mostafa Hassani 2.1 Introduction 21 2.2 Fundamentals of Impact Bonding 23 2.2.1 Plate Impacts and Explosive Welding 23 2.2.1.1 The Shock Equations of State 23 2.2.1.2 Limiting Conditions for Explosive Welding 24 2.2.2 Laser Impact Bonding 30 2.3 Bonding Mechanisms in Cold Spray 32 2.3.1 Proposed Mechanisms 32 2.3.1.1 The Role of Jetting and Impact Pressure in Particle Bonding 32 2.3.1.2 The Limiting Case of Impact Melting 33 2.3.1.3 Adiabatic Shear Instability 36 2.3.1.4 Dissimilar Materials Impact 40 2.3.2 Influence of Particle Characteristics 41 2.3.2.1 Particle Temperature 41 2.3.2.2 Particle Size 42 2.3.2.3 Surface Oxide and Hydroxide Effects 42 References 43 3 Microstructures and Microstructural Evolution in Cold-Sprayed Materials 49 Luke N. Brewer and Lorena I. Perez-Andrade 3.1 Introduction 49 3.2 Defect Structures 50 3.2.1 Vacancies 51 3.2.2 Dislocation Structure 52 3.2.3 Grain Structure 55 3.2.4 Precipitate Structure 56 3.2.5 Porosity 60 3.3 Microstructural Evolution of Thermally Treated Cold-Sprayed Materials 61 3.3.1 Recovery, Recrystallization, and Grain Growth 62 3.3.2 Precipitation 65 3.3.3 Heat Treatment of Feedstock Powders and its Impact on Microstructure 66 3.4 Conclusions 67 Acknowledgements 67 References 68 4 Mechanical Properties of Cold Spray Deposits 75 Sara Bagherifard and Mario Guagliano 4.1 Introduction 75 4.2 Mechanical Properties 76 4.2.1 Adhesive Strength 77 4.2.1.1 Adhesive Strength Test Methods 77 4.2.1.2 The Effect of Process Parameters on Adhesive Strength 80 4.2.1.3 The effect of Pre-/Post-treatments on Adhesive Strength 80 4.2.2 Cohesive Strength 83 4.2.2.1 Cohesive Strength Test methods 84 4.2.2.2 Cohesive Strength Under Static Loading 84 4.2.2.3 Cohesive Strength Under Fatigue Loading 86 4.2.2.4 Anisotropy in Cohesive Strength 90 4.2.3 Summary and Future Perspectives 91 References 94 5 Cold Spray in Practical and Potential Applications 101 Jingjie Wei, Yong He, Phuong Vo, and Yu Zou 5.1 Introduction 101 5.1.1 The Cold Spray Process 101 5.1.2 Cold Spray Additive Manufacturing (CSAM) 103 5.2 Materials 103 5.2.1 Cu and Cu Alloys 103 5.2.1.1 2Cu–Ga and Cu–In–Ga 107 5.2.1.2 Cu–Sn 107 5.2.1.3 Cu–W 107 5.2.2 Al and Al Alloys 108 5.2.3 Ni and Ni Alloys 110 5.2.4 Stainless Steels 111 5.2.5 Body Center Cubic (BCC) Metals 112 5.2.5.1 Tantalum 112 5.2.5.2 Niobium 114 5.2.6 Hexagonal Close-Packed (HCP) Metals 114 5.2.6.1 Titanium 114 5.2.6.2 Magnesium 116 5.2.7 Metal Mixes and Metal Matrix Composite (MMC) 116 5.2.7.1 Metal Mixes 117 5.2.7.2 Metal Matrix Composite 117 5.2.8 Multicomponent and High Entropy Alloys 120 5.2.8.1 MCrAlY Multicomponent Alloy 120 5.2.8.2 High Entropy Alloy (HEA) 120 5.2.9 Multimaterials 121 5.3 Perspective and Challenges 122 References 124 Part III Additive Friction Stir Deposition 133 6 Process Fundamentals of Additive Friction Stir Deposition 135 David Garcia and Hang Z. Yu 6.1 Additive Friction Stir Deposition – Macroscopic Process Overview 136 6.2 Thermo-Mechanical Processing Evolution 139 6.3 Heat Generation and Heat Transfer 142 6.3.1 Heat Generation and Heat Transfer Mechanisms 142 6.3.2 Peak Temperature and Material Dependence 143 6.4 Material Flow and Deformation 146 References 149 7 Dynamic Microstructure Evolution in Additive Friction Stir Deposition 153 Robert J. Griffiths and Hunter A. Rauch 7.1 Introduction to Microstructure Evolution in Additive Friction Stir Deposition 154 7.2 Dynamic Microstructure Evolution in Single-Phase Materials 155 7.2.1 Stacking Fault Energy and Dislocation Mobility 155 7.2.2 Dynamic Recovery 157 7.2.3 Continuous Dynamic Recrystallization 157 7.2.4 Discontinuous Dynamic Recrystallization 159 7.2.5 Static and Post-Dynamic Recrystallization 160 7.2.6 Heterogeneous Deposits and Metadynamic Recrystallization 161 7.3 Dynamic Microstructure Evolution in Multiple-Phase Materials 162 7.3.1 Thermal Evolution During Additive Friction Stir Deposition 162 7.3.2 Evolution of Secondary Phases at Low Temperature 164 7.3.3 Evolution of Secondary Phases at High Temperature 166 7.3.4 Evolution of Secondary Phases After Deformation 168 7.3.5 Mapping Secondary Phase Evolution to Processing Space 168 7.4 Effects of Material Transport on Microstructure Evolution 170 7.4.1 Mechanisms of Material Transport 170 7.4.2 Material Transport for the Homogenization of Mixtures 172 7.4.3 Densification of Material Through Material Transport 173 7.4.4 Material Transport and Spatial Variance in Thermomechanical Conditions 174 7.5 The Study of Microstructure Evolution in Additive Friction Stir Deposition 175 7.5.1 Contemporary Approaches 175 7.5.2 Novel Approaches 177 Acknowledgement 177 References 177 8 Mechanical Properties of Additive Friction Stir Deposits 181 Dustin Avery and Mackenzie Perry 8.1 Introduction 181 8.2 Magnesium-Based Alloys 184 8.2.1 WE43 184 8.2.2 AZ31 187 8.3 Aluminum-Based Alloys 189 8.3.1 5xxx 190 8.3.2 2xxx 192 8.3.3 6xxx 193 8.3.4 7xxx 195 8.3.5 Cast Al Alloys 197 8.4 Other Alloys Systems 197 8.4.1 Nickel-Based Alloys 197 8.4.2 Copper-Based Alloys 198 8.4.3 Titanium-Based Alloys 198 8.4.4 Steel Alloys 199 8.4.5 High-Entropy Alloys 199 8.4.6 Metal Matrix Composites 200 8.5 Repair 200 8.6 Summary and Future Perspectives 201 8.6.1 Anisotropy 201 8.6.2 Graphite Lubricant 202 8.6.3 Multimaterial or Designed Feedstock 202 8.6.4 Effect of Process Parameters on Mechanical Properties 202 8.6.5 Active Cooling/Heating 202 8.6.6 Heat Treatment 202 8.6.7 High-Temperature Materials – Tool Wear 203 8.6.8 Unique Possibilities 203 8.6.9 Modeling 203 References 203 9 Potential Industrial Applications of Additive Friction Stir Deposition 209 Hang Z. Yu, Rajiv S. Mishra, Chase D. Cox, and Zhili Feng 9.1 Large-Scale Metal Additive Manufacturing 209 9.2 Selective Area Cladding 211 9.3 Recycling and Upcycling 214 9.4 Structural Repair 220 9.5 Underwater Deposition 224 Acknowledgment 227 References 227 Part IV Ultrasonic Additive Manufacturing 231 10 Process Fundamentals of Ultrasonic Additive Manufacturing 233 Austin Ward 10.1 Process Overview 233 10.1.1 Process Parameters 234 10.2 Temperature Rise and Thermal Modeling 235 10.2.1 Heat Generation During Welding 235 10.2.2 Sonotrode Contact Stress 237 10.2.3 Coefficient of Friction 238 10.2.4 Temperature Profile 239 10.3 Feedstock Bonding Mechanisms 241 10.3.1 Oxide Breakdown 241 10.3.2 Asperity Deformation 243 10.3.3 Diffusional Bonding Processes 246 10.3.4 Liquid-Phase Bonding 247 10.4 Dissimilar Metal Consolidation 247 10.4.1 Mechanical and Thermal Modeling 247 10.4.2 Dissimilar Metal Junction Growth 248 10.4.3 Interdiffusion 249 10.5 Acoustic Softening and Strain Normality 251 10.5.1 Cyclic Strain Ratcheting 253 10.6 Summary 254 Acknowledgments 255 References 255 11 Ultrasonic Additive Manufacturing: Microstructural and Mechanical Characterization 259 Tianyang (Tyler) Han, Leon M. Headings, and Marcelo J. Dapino 11.1 Introduction 259 11.2 Microstructure Analysis of UAM Builds 259 11.2.1 Similar Material Joining with UAM 260 11.2.2 Dissimilar Material Joining with UAM 262 11.2.2.1 Al-Ceramic Weld 262 11.2.2.2 Ni-Steel Weld 263 11.3 Hardness Analysis of UAM Builds 266 11.4 Mechanical Characterization of UAM Builds 267 11.4.1 Design of a Custom Shear Testing Method 268 11.4.2 Validation of the Shear Test 268 11.4.3 Finite element Modeling of the Shear Test 270 11.4.4 Application of the Shear Test to UAM Samples 273 11.5 Conclusions 275 References 275 12 Industrial Applications of Ultrasonic Additive Manufacturing 279 Mark Norfolk 12.1 Early Years 279 12.2 Increased Power → Increased Capability 281 12.3 Modern Applications 282 12.3.1 Electrification 282 12.3.2 Thermal Management 286 12.3.3 Embedded Electronics 288 12.3.3.1 SmartPlate 290 12.3.3.2 SensePipe 291 12.4 Future Applications 292 References 292 Part V Sintering-Based Processes 295 13 Principles of Solid-State Sintering 297 Basil J. Paudel, Albert C. To, and Amir Mostafaei 13.1 Introduction 297 13.2 Basic Terminology 298 13.2.1 Sintering 298 13.2.2 Relative Density/Green Density 299 13.2.3 Coordination Number 299 13.2.4 Surface Tension/Surface Energy 300 13.2.5 Wetting Angle/Dihedral Angle 300 13.2.6 Neck Growth/Shrinkage/Densification 301 13.3 Sintering Stress 302 13.3.1 Two Particle Model 302 13.3.1.1 Case I: Without Shrinkage 303 13.3.1.2 Case II: With Shrinkage 303 13.3.2 Driving Force 303 13.3.3 Interfacial Activity/Thermodynamics 304 13.4 Mass Transport Mechanisms 306 13.4.1 Grain Boundary Diffusion 306 13.4.2 Lattice/Volume Diffusion 306 13.4.3 Viscous Flow 306 13.4.4 Surface Diffusion 307 13.4.5 Evaporation/Condensation 307 13.4.6 Gas Diffusion 307 13.5 Sintering Stages 307 13.6 Sintering Simulation 308 13.7 Concluding Remarks, Challenges, and Future Works 309 References 310 14 Material Extrusion Additive Manufacturing 313 Alexander C. Barbati and Aaron Preston 14.1 Introduction 313 14.2 Hierarchy of MEAM Parts and Feedstock Behavior 316 14.3 Feedstock Attributes 325 14.4 Extrusion Control 327 14.5 Toolpathing: Strength and Quality 331 14.6 Conclusions 335 Acknowledgments 336 References 336 15 Binder Jetting-based Metal Printing 339 Marco Mariani, Nora Lecis, and Amir Mostafaei 15.1 Introduction to Binder Jetting 339 15.2 Printing Phase 341 15.2.1 Particulate Feedstock 341 15.2.1.1 Feedstock Materials 342 15.2.1.2 Feedstock Morphology and Size Distribution 343 15.2.2 Binder Selection 344 15.2.3 Powder Spreading and Binder Deposition System Configurations 345 15.3 Thermal Treatments 346 15.3.1 Curing 346 15.3.2 Debinding 347 15.3.3 Sintering 348 15.3.4 Additional Treatments 349 15.4 Future Developments 350 15.5 Conclusion 352 References 352 16 Sintering-based Metal Additive Manufacturing Methods for Magnetic Materials 361 H. Wang, A. M. Elliot, and M. P. Paranthaman 16.1 Introduction 361 16.2 Background 362 16.3 Additive Manufacturing Methods 369 16.4 Applications 372 16.5 Summary 374 Acknowledgments 375 References 375 17 Future Perspectives 379 Hang Z. Yu, Nihan Tuncer, and Zhili Feng 17.1 Enhancing the Understanding of Process Fundamentals 379 17.2 Expanding the Printable Material Library 381 17.3 Embracing Artificial Intelligence for Quality Control and Process Prediction 381 References 383 Index 385
Hang Z. Yu, PhD, is an Associate Professor in the Department of Materials Science and Engineering at Virginia Tech, USA. His research focuses on materials processing and manufacturing science, emphasizing the underlying process physics, mechanics, and kinetics. His work also aims to leverage the process fundamentals to drive material sustainability to new heights, e.g., via solid-state metal recycling, structural repair, and austere condition-resilient manufacturing. Nihan Tuncer, PhD, is a Principal Scientist at Desktop Metal Inc. since 2016, where she has been developing solid-state 3D printing technologies and equipment. She holds several patents in addition to research papers and review articles. Her expertise includes powder metallurgy, processing-microstructure-property relationships in ferrous and non-ferrous alloys, porous metals, and shape memory alloys. Zhili Feng, PhD, currently leads the Materials Joining Group and is a Distinguished R&D Staff Member of Oak Ridge National Laboratory, USA. His research covers various aspects of thermal-mechanical-metallurgical behaviors of materials in materials joining.