Since their discovery in 2011, MXenes (2D carbides, nitrides, and carbonitrides of early transition metals) have developed into one of the largest and most intensively studied families of 2D materials. They offer unique properties and are being explored in a large variety of applications. This book compiles the most important research from a pioneer of the field, Professor Yury Gogotsi, and his interdisciplinary research team, as well as numerous collaborators worldwide. It reports on the discovery and rise of MXenes and describes their synthesis and processing, properties, and incorporation into polymer, ceramic, and metal matrices to produce composites. It also discusses the potential of MXenes for use in energy storage, optics, electronics, and sensing, as well as biomedical, environmental, and electrocatalysis applications. The book will appeal to anyone interested in nanomaterials and their synthesis, properties, and applications.
Edited by:
Yury Gogotsi (Drexel University Philadelphia Pennsylvania USA)
Imprint: Jenny Stanford Publishing
Country of Publication: Singapore
Dimensions:
Height: 229mm,
Width: 152mm,
Weight: 2.200kg
ISBN: 9789814877954
ISBN 10: 9814877956
Pages: 1070
Publication Date: 24 August 2023
Audience:
College/higher education
,
Primary
Format: Hardback
Publisher's Status: Active
INTRODUCTION 1. The Rise of MXenes Yury Gogotsi and Babak Anasori DISCOVERY 2. Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2 Michael Naguib, Murat Kurtoglu, Volker Presser, Jun Lu, Junjie Niu, Min Heon, Lars Hultman, Yury Gogotsi, and Michel W. Barsoum 3. Two-Dimensional Transition Metal Carbides Michael Naguib, Olha Mashtalir, Joshua Carle, Volker Presser, Jun Lu, Lars Hultman, Yury Gogotsi, and Michel W. Barsoum 4. Two-Dimensional, Ordered, Double Transition Metals Carbides Babak Anasori, Yu Xie, Majid Beidaghi, Jun Lu, Brian C. Hosler, Lars Hultman, Paul R. C. Kent, Yury Gogotsi, and Michel W. Barsoum 5. Synthesis of Two-Dimensional Titanium Nitride Ti4N3 Patrick Urbankowski, Babak Anasori, Taron Makaryan, Dequan Er, Sankalp Kota, Patrick L. Walsh, Mengqiang Zhao, Vivek B. Shenoy, Michel W. Barsoum, and Yury Gogotsi 6. Synthesis of Mo4VAlC4 MAX Phase and Two-Dimensional Mo4VC4 MXene with Five Atomic Layers of Transition Metals Grayson Deysher, Christopher Eugene Shuck, Kanit Hantanasirisakul, Nathan C. Frey, Alexandre C. Foucher, Kathleen Maleski, Asia Sarycheva, Vivek B. Shenoy, Eric A. Stach, Babak Anasori, and Yury Gogotsi PROPERTIES 7. Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides Kanit Hantanasirisakul and Yury Gogotsi 8. Elastic Properties of 2D Ti3C2Tx MXene Monolayers and Bilayers Alexey Lipatov, Haidong Lu, Mohamed Alhabeb, Babak Anasori, Alexei Gruverman, Yury Gogotsi, and Alexander Sinitskii 9. Control of MXenes’ Electronic Properties through Termination and Intercalation James L. Hart, Kanit Hantanasirisakul, Andrew C. Lang, Babak Anasori, David Pinto, Yevheniy Pivak, J. Tijn van Omme, Steven J. May, Yury Gogotsi, and Mitra L. Taheri 10. High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis Mykola Seredych, Christopher Eugene Shuck, David Pinto, Mohamed Alhabeb, Eliot Precetti, Grayson Deysher, Babak Anasori, Narendra Kurra, and Yury Gogotsi 11. Electrochromic Effect in Titanium Carbide MXene Thin Films Produced by Dip-Coating Pol Salles, David Pinto, Kanit Hantanasirisakul, Kathleen Maleski, Christopher E. Shuck, and Yury Gogotsi 12. Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene Kanit Hantanasirisakul, Mohamed Alhabeb, Alexey Lipatov, Kathleen Maleski, Babak Anasori, Pol Salles, Chanoknan Ieosakulrat, Pasit Pakawatpanurut, Alexander Sinitskii, Steven J. May, and Yury Gogotsi 13. Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2Tx MXene Asia Sarycheva and Yury Gogotsi SYNTHESIS AND PROCESSING 14. Intercalation and Delamination of Layered Carbides and Carbonitrides Olha Mashtalir, Michael Naguib, Vadym N. Mochalin, Yohan Dall’Agnese, Min Heon, Michel W. Barsoum, and Yury Gogotsi 15. Conductive Two-Dimensional Titanium Carbide ‘Clay’ with High Volumetric Capacitance Michael Ghidiu, Maria R. Lukatskaya, Meng-Qiang Zhao, Yury Gogotsi, and Michel W. Barsoum 16. Amine-Assisted Delamination of Nb2C MXene for Li-Ion Energy Storage Devices Olha Mashtalir, Maria R. Lukatskaya, Meng-Qiang Zhao, Michel W. Barsoum, and Yury Gogotsi 17. Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide Mohamed Alhabeb, Kathleen Maleski, Babak Anasori, Pavel Lelyukh, Leah Clark, Saleesha Sin, and Yury Gogotsi 18. Selective Etching of Silicon from Ti3SiC2 (MAX) to Obtain 2D Titanium Carbide (MXene) Mohamed Alhabeb, Kathleen Maleski, Tyler S. Mathis, Asia Sarycheva, Christine B. Hatter, Simge Uzun, Ariana Levitt, and Yury Gogotsi 19. Additive-Free MXene Inks and Direct Printing of Micro-Supercapacitors Chuanfang (John) Zhang, Lorcan McKeon, Matthias P. Kremer, Sang-Hoon Park, Oskar Ronan, Andrés Seral-Ascaso, Sebastian Barwich, Cormac Ó Coileáin, Niall McEvoy, Hannah C. Nerl, Babak Anasori, Jonathan N. Coleman, Yury Gogotsi, and Valeria Nicolosi 20. Additive-Free MXene Liquid Crystals and Fibers Jizhen Zhang, Simge Uzun, Shayan Seyedin, Peter A. Lynch, Bilen Akuzum, Zhiyu Wang, Si Qin, Mohamed Alhabeb, Christopher E. Shuck, Weiwei Lei, E. Caglan Kumbur, Wenrong Yang, Xungai Wang, Genevieve Dion, Joselito M. Razal, and Yury Gogotsi 21. Scalable Manufacturing of Free-Standing, Strong Ti3C2Tx MXene Films with Outstanding Conductivity Jizhen Zhang, Na Kong, Simge Uzun, Ariana Levitt, Shayan Seyedin, Peter A. Lynch, Si Qin, Meikang Han, Wenrong Yang, Jingquan Liu, Xungai Wang, Yury Gogotsi, and Joselito M. Razal 22. Scalable Synthesis of Ti3C2Tx MXene Christopher E. Shuck, Asia Sarycheva, Mark Anayee, Ariana Levitt, Yuanzhe Zhu, Simge Uzun, Vitaliy Balitskiy, Veronika Zahorodna, Oleksiy Gogotsi, and Yury Gogotsi COMPOSITES 23. Flexible and Conductive MXene Films and Nanocomposites with High Capacitance Zheng Ling, Chang E. Ren, Meng-Qiang Zhao, Jian Yang, James M. Giammarco, Jieshan Qiu, Michel W. Barsoum, and Yury Gogotsi 24. Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance Jun Yan, Chang E. Ren, Kathleen Maleski, Christine B. Hatter, Babak Anasori, Patrick Urbankowski, Asya Sarycheva, and Yury Gogotsi 25. Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxide Jing Guo, Benjamin Legum, Babak Anasori, Ke Wang, Pavel Lelyukh, Yury Gogotsi, and Clive A Randall 26. Colloidal Gelation in Liquid Metals Enables Functional Nanocomposites of 2D Metal Carbides and Lightweight Metals Vladislav Kamysbayev, Nicole M. James, Alexander S. Filatov, Vishwas Srivastava, Babak Anasori, Heinrich M Jaeger, Yury Gogotsi, and Dmitri V. Talapin ENERGY STORAGE 27. MXene: A Promising Transition Metal Carbide Anode for Lithium-Ion Batteries Michael Naguib, Jérémy Come, Boris Dyatkin, Volker Presser, Pierre-Louis Taberna, Patrice Simon, Michel W. Barsoum, and Yury Gogotsi 28. Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide Maria R. Lukatskaya, Olha Mashtalir, Chang E. Ren, Yohan Dall’Agnese, Patrick Rozier, Pierre Louis Taberna, Michael Naguib, Patrice Simon, Michel W. Barsoum, and Yury Gogotsi 29. 2D Metal Carbides and Nitrides for Energy Storage Babak Anasori, Maria R. Lukatskaya, and Yury Gogotsi 30. Ultra-High-Rate Pseudocapacitive Energy Storage in Two-Dimensional Transition Metal Carbides Maria R. Lukatskaya, Sankalp Kota, Zifeng Lin, Meng-Qiang Zhao, Netanel Shpigel, Mikhael D. Levi, Joseph Halim, Pierre-Louis Taberna, Michel W. Barsoum, Patrice Simon, and Yury Gogotsi 31. Thickness-Independent Capacitance of Vertically Aligned Liquid-Crystalline MXenes Yu Xia, Tyler S. Mathis, Meng-Qiang Zhao, Babak Anasori, Alei Dang, Zehang Zhou, Hyesung Cho, Yury Gogotsi, and Shu Yang 32. High Capacity Silicon Anodes Enabled by MXene Viscous Aqueous Ink Chuanfang (John) Zhang, Sang-Hoon Park, Andrés Seral-Ascaso, Sebastian Barwich, Niall McEvoy, Conor S. Boland, Jonathan N. Coleman, Yury Gogotsi, and Valeria Nicolosi 33. Influences from Solvents on Charge Storage in Titanium Carbide MXenes Xuehang Wang, Tyler S. Mathis, Ke Li, Zifeng Lin, Lukas Vlcek, Takeshi Torita, Naresh C. Osti, Christine Hatter, Patrick Urbankowski, Asia Sarycheva, Madhusudan Tyagi, Eugene Mamontov, Patrice Simon, and Yury Gogotsi BIOMEDICAL, ENVIRONMENTAL, AND CATALYTIC APPLICATIONS 34. Charge- and Size-Selective Ion Sieving through Ti3C2Tx MXene Membranes Chang E. Ren, Kelsey B. Hatzell, Mohamed Alhabeb, Zheng Ling, Khaled A. Mahmoud, and Yury Gogotsi 35. Single Platinum Atoms Immobilized on an MXene as an Efficient Catalyst for the Hydrogen Evolution Reaction Jinqiang Zhang, Yufei Zhao, Xin Guo, Chen Chen, Chung-Li Dong, Ru-Shi Liu, Chih-Pin Han, Yadong Li, Yury Gogotsi, and Guoxiu Wang 36. MXene Molecular Sieving Membranes for Highly Efficient Gas Separation Li Ding, Yanying Wei, Libo Li, Tao Zhang, Haihui Wang, Jian Xue, Liang-Xin Ding, Suqing Wang, Jürgen Caro, and Yury Gogotsi 37. MXene Sorbents for Removal of Urea from Dialysate: A Step toward the Wearable Artificial Kidney Fayan Meng, Mykola Seredych, Chi Chen, Victor Gura, Sergey Mikhalovsky, Susan Sandeman, Ganesh Ingavle, Tochukwu Ozulumba, Ling Miao, Babak Anasori, and Yury Gogotsi 38. A Gel-Free Ti3C2Tx-Based Electrode Array for High-Density, High-Resolution Surface Electromyography Brendan B. Murphy, Patrick J. Mulcahey, Nicolette Driscoll, Andrew G. Richardson, Gregory T. Robbins, Nicholas V. Apollo, Kathleen Maleski, Timothy H. Lucas, Yury Gogotsi, Timothy Dillingham, and Flavia Vitale APPLICATIONS IN OPTICS, ELECTRONICS AND SENSING 39. Electromagnetic Interference Shielding with 2D Transition Metal Carbides Faisal Shahzad, Mohamed Alhabeb, Christine B. Hatter, Babak Anasori, Soon Man Hong, Chong Min Koo, and Yury Gogotsi 40. 2D Titanium Carbide for Wireless Communication Asia Sarycheva, Alessia Polemi, Yuqiao Liu, Kapil Dandekar, Babak Anasori, and Yury Gogotsi 41. Metallic Ti3C2Tx MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio Seon Joon Kim, Hyeong-Jun Koh, Chang E. Ren, Ohmin Kwon, Kathleen Maleski, Soo-Yeon Cho, Babak Anasori, Choong-Ki Kim, Yang-Kyu Choi, Jihan Kim, Yury Gogotsi, and Hee-Tae Jung 42. Surface-Modified Metallic Ti3C2Tx MXene as Electron Transport Layer for Planar Heterojunction Perovskite Solar Cells Lin Yang, Chunxiang Dall’Agnese, Yohan Dall’Agnese, Gang Chen, Yu Gao, Yoshitaka Sanehira, Ajay Kumar Jena, Xiao-Feng Wang, Yury Gogotsi, and Tsutomu Miyasaka 43. Anomalous Absorption of Electromagnetic Waves by 2D Transition Metal Carbonitride Ti3CNTx Aamir Iqbal, Faisal Shahzad, Kanit Hantanasirisakul, Myung-Ki Kim, Jisung Kwon, Junpyo Hong, Hyerim Kim, Daesin Kim, Yury Gogotsi, Chong Min Koo 44. Beyond Ti3C2Tx: MXenes for Electromagnetic Interference Shielding Meikang Han, Christopher Eugene Shuck, Roman Rakhmanov, David Parchment, Babak Anasori, Chong Min Koo, Gary Friedman, and Yury Gogotsi
Yury Gogotsi is director of the A.J. Drexel Nanomaterials Institute, Distinguished University Professor and Charles T. and Ruth M. Bach Professor of Materials Science and Engineering at Drexel University. He received his MS in metallurgy (1984) and PhD in physical chemistry (1986) from Kyiv Polytechnic and DSc degree from the Ukrainian Academy of Sciences in 1995. He works on 2D carbides and nitrides (MXenes), which he discovered with his students and collaborators, and their applications in energy, environmental protection, electronics, and medicine.
Reviews for MXenes: From Discovery to Applications of Two-Dimensional Metal Carbides and Nitrides
"""This book collects some important publications on MXenes, discovered by Prof. Yury Gogotsi and his colleagues Prof. Michel Barsoum and Dr Michael Naguib. MXene is a rising star in two-dimensional materials and shows its great potential in electrochemical storage, electromagnetic interference shielding, optoelectronics, catalysts, and medicine. Readers will get to know how this wonderful material was born at Drexel University and what a splendid journey it has been to understand its structure–property relationships."" —Prof. Qing Huang, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, China"
