Discover the cutting-edge progress of a promising class of materials significant for use in energy technologies as catalysts
Materials are said to be metastable-phases if they can retain their stability when subjected only to slight disturbances. Materials in metastable-phases can have very different properties from those in a state of equilibrium, and can perform very differently under conditions of experimentation, work, or industrial use. Metastable-phase materials are therefore a promising area of study in a variety of different fields, including cutting-edge industries.
Metastable-Phase Materials constitute a wide-ranging overview of these materials, their properties, and their applications. Beginning with an overall characterization of metastable-phase materials and their normal modes of synthesis, it characterizes the most important branch of metastable-phase materials and reviews a range of catalytic applications. The result is a critical contribution to materials science and catalytic chemistry with potentially far-reaching implications.
Metastable-Phase Materials readers will also find:
Treatment of metastable-phase metal materials, 2D metastable-phase materials, and spin-dependent metastable-phase materials Detailed discussion of metastable-phase material applications in electrocatalysis, photocatalysis, thermalcatalysis, and more State-of-the-art technological applications in a myriad of areas
Metastable-Phase Materials are ideal for materials scientists, catalytic chemists, inorganic chemists, photochemists, electrochemists, organic chemists, and the libraries that serve these communities.
Foreword xi Preface xiii 1 Introduction of the Metastable-Phase Materials 1 Qi Shao and Mingwang Shao 1.1 Introduction 1 1.2 What Are Metastable-Phase Materials? 1 1.3 The Categories of Metastable-Phase Materials 2 1.4 The Influence on Polymorphs of Materials 6 1.5 The Wide Applications of Metastable-Phase Materials 8 1.6 The Criterion for Stable-Phase and Metastable-Phase Materials 8 References 10 2 Synthetic Methodology 15 Qi Shao 2.1 Introduction 15 2.2 The Key for Synthesizing Metastable-Phase Materials 15 2.3 The Synthetic Methods for Synthesizing Metastable-Phase Materials 16 References 25 3 Characterization 33 Qi Shao 3.1 Introduction 33 3.2 Characterizations 33 3.3 How to Determine the Phase of Metastable-Phase 2D Metal Oxides 43 References 45 4 Metastable-Phase Metals 51 Qi Shao 4.1 Introduction 51 4.2 Noble Metals 51 4.3 Non-noble Metals 60 4.4 The Criterion to Determine the Stable-Phase and Metastable-Phase Metals 64 References 66 5 Metastable-Phase Oxide, Chalcogenide, Phosphide, and Boride Materials 71 Qi Shao 5.1 Introduction 71 5.2 Oxides 71 5.3 Chalcogenides 76 5.4 Others 78 References 80 6 Spin-Dependent Metastable-Phase Materials 85 Qi Shao 6.1 Introduction 85 6.2 Spin-Related Catalysis 85 6.3 Spin-Related Catalysts for Alkaline OER 88 6.4 Spin-Related Catalyst for Acidic OER 89 References 90 7 Crystallography, Design, and Synthesis of Two-Dimensional Metastable-Phase Oxides 93 Mingwang Shao and Qi Shao 7.1 Introduction 93 7.2 The Point Group, Crystal System, Crystal Lattice, and Space Groups of 2D Materials 93 7.3 The Possible Crystal Structures and Chemical Formula of 2D Metal Oxides 100 7.4 How to Prepare Metastable-Phase 2D Metal Oxides 119 7.5 2D Metastable-Phase Noble Metal Oxides 120 7.6 Metastable-Phase 2D Non-noble Metal Oxides 126 7.7 The Covalent Bond Behavior in Metastable-Phase 1T Metal Oxides 129 References 134 8 Electrocatalysis 141 Qi Shao 8.1 Introduction 141 8.2 Several Typical Electrochemical Reactions 141 8.3 Metastable-Phase Catalysts for Advanced Electrocatalysis 145 References 167 9 Photocatalysis 173 Mingwang Shao and Zhenhui Kang 9.1 Introduction 173 9.2 Fundamental Concepts of Photocatalysis 173 9.3 Metastable-Phase Catalysts and Photocatalysis 177 9.4 The Advantages and Disadvantages of Photocatalysis 182 References 183 10 Thermocatalysts 191 Qi Shao 10.1 Introduction 191 10.2 Several Typical Thermocatalytic Reactions 191 10.3 Metastable-Phase Catalysts for Thermocatalysis 193 References 201 Summary and Outlook 207 Index 209
Qi Shao, PhD, is an associate professor at the College of Chemistry, Chemical Engineering and Materials Science, Soochow University, China. She received her PhD in applied physics from City University of Hong Kong in 2016. Zhenhui Kang, PhD, is currently a professor at the Institute of Functional Nano & Soft Materials (FUNSOM) and the Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices in Soochow University, China. Mingwang Shao, PhD, is a professor at the Institute of Functional Nano & Soft Materials (FUNSOM) and the Jiangsu Key Laboratory for Cabon-Based Functional Materials and Devices, Soochow University, China. He received his PhD from the University of Science and Technology of China in 2003.
