Handbook of Smart Coatings for Materials Protection

Contributor contact details Woodhead Publishing Series in Metals and Surface Engineering Preface Part I: Fundamentals of smart coatings for materials protection 1. Corrosion processes and strategies for prevention: an introduction Abstract: 1.1 Introduction 1.2 Corrosion of metals, alloys and composites: an overview 1.3 Wet corrosive environments 1.4 Strategies for corrosion inhibition: design and materials 1.5 Strategies for corrosion inhibition: protective coatings 1.6 Conclusion 1.7 Acknowledgement 1.8 References 2. Smart coatings for corrosion protection: an overview Abstract: 2.1 Introduction 2.2 Triggering mechanisms 2.3 Self-healing mechanisms 2.4 Sensing systems 2.5 Future trends 2.6 Conclusion 2.7 Acknowledgement 2.8 References 3. Techniques for synthesizing and applying smart coatings for material protection Abstract: 3.1 Introduction 3.2 Environmentally friendly smart self-healing coatings 3.3 Most common methods and technologies for synthesizing smart coatings 3.4 Conclusion 3.5 References 4. Multi-functional, self-healing coatings for corrosion protection: materials, design and processing Abstract: 4.1 Introduction 4.2 Key issues in developing multi-functional coatings 4.3 Materials for encapsulation of self-healing and anti-corrosion agents 4.4 Computer-based simulation 4.5 Material testing and function screening 4.6 Processing 4.7 Guiding principles for designing multi-functional coatings 4.8 Case studies and examples 4.9 Conclusion and future trends 4.10 Acknowledgements 4.11 References 5. Strategies for developing multi-functional, self-healing coatings for corrosion prevention and other functions Abstract: 5.1 Introduction 5.2 Approaches to self-healing of functional coatings 5.3 Corrosion and other functions of coatings recovered or enhanced by self-healing 5.4 Technologies for creating functional self-healing coatings 5.5 Conclusion 5.6 Future trends 5.7 Sources of further information and advice 5.8 References 6. Protective coatings for automotive, aerospace and military applications: current prospects and future trends Abstract: 6.1 Introduction 6.2 Advances in materials of construction 6.3 Advances in surface pre-treatment 6.4 Advances in top organic coatings 6.5 Optimising the coatings process and testing 6.6 Conclusion and future trends 6.7 References Part II: Smart coatings with self-healing properties for corrosion protection 7. The use of nano-/microlayers, self-healing and slow-release coatings to prevent corrosion and biofouling Abstract: 7.1 Introduction 7.2 Corrosion of different metals: mechanisms, monitoring and corrosion inhibitors 7.3 Microbiologically influenced corrosion (MIC) and biofouling: mechanisms, monitoring and control 7.4 Inhibition of corrosion and biofilm formation by nanolayers 7.5 Self-healing coatings against corrosion and biofilm formation with nano-/microcapsules and nano-/microspheres 7.6 Conclusion 7.7 References and further reading 8. Self-healing anti-corrosion coatings for applications in structural and petrochemical engineering Abstract: 8.1 Introduction 8.2 Self-healing mechanisms 8.3 Self-healing anti-corrosion coatings based on polyaniline (PANI)-modified ferrites 8.4 Self-healing anti-corrosion coatings based on conducting polymer-modified graphene 8.5 Conducting polymer coatings based on PANI-modified TiO2 8.6 Self-healing anti-corrosion coatings using the layer-by-layer approach 8.7 Conclusion and future trends 8.8 References 9. Smart nanocoatings for corrosion detection and control Abstract: 9.1 Introduction 9.2 Smart anti-corrosion nanocoatings 9.3 Smart self-healing coatings using microcapsules 9.4 Synthesis of microcapsules 9.5 Physical and mechanical properties of self-healing coatings 9.6 Smart nanocoatings for specific applications 9.7 Smart self-cleaning nanocoatings 9.8 Applications of smart nanocoatings 9.9 Conclusion and future trends 9.10 References 10. Smart self-healing coatings for corrosion protection of aluminium alloys Abstract: 10.1 Introduction 10.2 Corrosion of aluminium alloys 10.3 Conversion coatings with self-healing properties 10.4 Hybrid sol–gel self-healing coatings 10.5 Sol–gel coatings with corrosion inhibitors 10.6 Multilayer coatings combining sol–gel coatings and corrosion inhibitors 10.7 Organic polymeric coatings with self-healing properties 10.8 Smart organic coating systems with controlled inhibitor release 10.9 Smart coatings with micro- and nanocontainers 10.10 Conclusion and future trends 10.11 References 11. Smart stannate-based self-healing coatings for corrosion protection of magnesium alloys Abstract: 11.1 Introduction 11.2 Developing and testing stannate-based smart coatings 11.3 The performance of stannate-based smart coatings 11.4 Conclusion 11.5 Acknowledgments 11.6 References 12. Incorporating microcapsules in smart coatings for corrosion protection of steel Abstract: 12.1 Introduction 12.2 Mechanisms of self-healing in smart anticorrosion coatings 12.3 Synthesis of microcapsules 12.4 Characterization of microcapsules 12.5 Testing the effectiveness of coatings 12.6 Conclusion 12.7 Acknowledgments 12.8 References 13. Multi-layer smart coatings for corrosion protection of aluminium alloys and steel Abstract: 13.1 Introduction 13.2 Developing layer-by-layer (LbL) coatings with active feedback properties 13.3 Methods for formation of LbL coatings 13.4 Case studies 13.5 Conclusion and future trends 13.6 References and further reading 14. Electro-active polymer (EAP) coatings for corrosion protection of metals Abstract: 14.1 Introduction 14.2 The use of electro-active polymers (EAPs) in corrosion protection 14.3 Synthesis and properties of particular EAPs 14.4 Toxicological properties of poly(2,5-(bis-N-methyl-N-hexylamino) phenylene vinylene (BAM-PPV) 14.5 Methods to evaluate corrosion-inhibiting properties of EAPs 14.6 Corrosion inhibition of ferrous metals using EAP coatings 14.7 Corrosion inhibition of aluminum alloys using EAP coatings 14.8 Future trends 14.9 Conclusion 14.10 Acknowledgment 14.11 References 15. Microencapsulated indicators and inhibitors for corrosion detection and control Abstract: 15.1 Introduction 15.2 Corrosion indicators and corrosion sensing 15.3 Corrosion inhibitor delivery systems 15.4 Current developments in smart coatings for corrosion sensing and inhibition 15.5 pH-sensitive microcapsules and microparticles 15.6 Microencapsulation methods 15.7 Microcapsules and microparticles for corrosion indication 15.8 Microcapsules and microparticles for corrosion inhibition 15.9 Conclusion 15.10 Acknowledgments 15.10 References 15.12 Appendix: list of acronyms Part III: Other types of smart coating 16. Smart acrylic coatings containing silica particles for corrosion protection of aluminum and other metals Abstract: 16.1 Introduction 16.2 The use of acrylic polymers in coatings 16.3 Synthesis and characterization of novel acrylic-based copolymers 16.4 Sol–gel incorporation of silica nanoparticles 16.5 Analyzing crosslinking and key properties in the coating 16.6 Conclusion 16.7 Acknowledgments 16.8 References 17. Recent advances in polyaniline (PANI)-based organic coatings for corrosion protection Abstract: 17.1 Introduction 17.2 Polyaniline (PANI) as an intrinsically conductive polymer (ICP) 17.3 PANI as an anti-corrosion polymer 17.4 Mechanisms of PANI as a barrier protective coating 17.5 Mechanism of PANI as a corrosion inhibitor 17.6 Mechanism of PANI in self-healing coatings with controlled inhibitor release 17.7 Conclusion and future trends 17.8 References 18. Smart self-cleaning coatings for corrosion protection Abstract: 18.1 Introduction 18.2 Types of self-cleaning coatings 18.3 Techniques for developing self-cleaning coatings 18.4 TiO2 as a material for corrosion protection 18.5 Conclusion 18.6 Future trends 18.7 References 19. Smart polymer nanocomposite water and oil repellent coatings for aluminum Abstract: 19.1 Introduction 19.2 Developing super-hydrophobic coatings: materials, processing and characterization 19.3 Flame treatment for super-hydrophobicity 19.4 Assessing coating properties 19.5 Electrical characteristics of the super-hydrophobic coatings 19.6 Conclusion 19.7 References 20. UV-curable organic polymer coatings for corrosion protection of steel Abstract: 20.1 Introduction 20.2 UV-cured coatings: materials and mechanisms of crosslinking 20.3 Additives and pigments 20.4 Case studies 20.5 Conclusion 20.6 Sources of further information and advice 20.7 References 21. Smart epoxy coatings for early detection of corrosion in steel and aluminum Abstract: 21.1 Introduction 21.2 In situ early corrosion detection via indicator molecules embedded in a protective coating 21.3 Early detection of steel corrosion via ‘turn-on’ fluorescence 21.4 Sensing mechanism of the corrosion indicator 21.5 Early detection of aluminum corrosion via ‘turn-on’ fluorescence 21.6 Future trends 21.7 Conclusion 21.8 References 22. Structural ceramics with self-healing properties Abstract: 22.1 Introduction 22.2 Material development 22.3 Self-crack-healing behavior 22.4 High-temperature strength of crack-healed specimen 22.5 Crack-healing behavior during service 22.6 Conclusion 22.7 References Index