Electronic Energy Levels of Transition Metal Complexes

Roman Boča (University of Ss Cyril and Methodius, Trnava, Slovakia)

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English

Elsevier - Health Sciences Division
25 November 2024

Inorganic chemistry; Metals technology & metallurgy

Electronic Energy Levels of Transition Metal Complexes guides the reader to understand how to comprehensively calculate (predict, reconstruct) electronic energy levels of separation between 0,1 to 30,000 cm-1 in d1 to d9 transition metal complexes. The applied apparatus helps to understand the individual effect of the interelectron repulsion, crystal field strength, spin-orbit coupling and the magnetic field for any symmetry. Symmetry labels can be attached to energy levels (eigenvalues) by analyzing the eigenvectors of the model Hamiltonian either at the level of crystal-field terms or crystal-field multiplets.

This book includes basic formulae for matrix elements of the model Hamiltonian and a huge number of results presented as graphs identifying the order of the energy levels and their labelling using the group (double group) irreducible representations. Utilization of the generated energy levels in electron spectroscopy, electron spin resonance and magnetochemistry is presented. Massive modelling was done using the desktop computers.

By: Roman Boča (University of Ss Cyril and Methodius Trnava Slovakia)
Imprint: Elsevier - Health Sciences Division
Country of Publication: United States
Dimensions: Height: 276mm, Width: 216mm,
ISBN: 9780443334160
ISBN 10: 0443334161
Pages: 398
Publication Date: 25 November 2024
Audience: Professional and scholarly , Undergraduate
Format: Paperback
Publisher's Status: Active

1. Symmetry 2. Electronic levels in a free atom 3. Electronic levels in a crystal field 4. Electronic spectra of transition metal complexes 5. Magnetism of transition metal complexes 6. Electron spin resonance of transition metal complexes 7. High energy spectroscopy 8. Key properties of d-electron configurations

Roman Boča works at the University of Ss Cyril and Methodius in Trnava, Slovakia.