"This book is based on an international symposium on ""Polymers for Cosmetics and Personal Care"" held at the 244th National ACS Meeting in Philadelphia on August 22, 2012. The aim of this book is to cover the many facets of polymers used in cosmetics and personal care products and to bring together researchers from industries and academic disciplines from different countries. To our knowledge, this is the first compilation of progress made in the use of polymers in cosmetics and personal industry.
This book comprises a collection of papers presented in the symposium as well as several review chapters. Topics in this book have been divided into three sections as follows: Part 1 contains reviews focused on polymers described in this book, polymers used in colored cosmetic products, and organo functional silicones; Part 2 is dedicated to new synthetic methods and strategies; and Part 3 is focused on novel applications of synthetic polymers.
In the synthetic portion of the book (Part 2), there are seven chapters.
Some chapters discuss specific approaches to controlling molecular architecture and other chapters prepare novel polymeric structures. For example, polymer structures can be controlled using free radical methods in order to prepare unique aqueous rheology modifiers or to create copolymers with unique properties. Additionally, novel materials prepared by combining poly(alphaolefins) with diphenylamine and polymers, novel cationic latex materials, and polymers with unique personal care attributes that are also biodegradable are discussed as well. There are chapters on structure-property relationship as well as on non-penetratingpolymerized surfactants.
The third part of the book consists of seven chapters, too. It highlights novel applications of materials that may not be typically associated with personal care products. Such polymers include acetylene-based polymers, alkylacrylate cross-polymers, styrene/acrylate copolymers, and silicones. There are also some chapters that discuss other interesting applications of materials by utilizing the enhanced performance they impart to personal care (e.g., ion permeable microcapsules and a polymer adsorption model).
This book will be a good resource for those involved in the field of personal care and cosmetics who want to learn of recent developments. Additionally, this book will benefit the reader that would like to become acquainted with the variety of polymeric systems that can be used in personal care products and cosmetics."
Preface .............................................................................................................................. ix Part 1: Reviews 1. Polymers for Personal Care and Cosmetics: Overview ....................................... 3 Anjali Patil and Michael S. Ferritto 2. Cosmetic Science and Polymer Chemistry: Perfect Together ........................... 13 Anjali Patil and Robert W. Sandewicz 3. Organo Functional Silicones in Personal Care .................................................... 39 Tony O'Lenick and Thomas O'Lenick Part 2: Synthesis 4. Modern Polyurethanes: Overview of Structure Property Relationship ........... 65 Yuliya Berezkin and Marie Urick 5. A Novel Cationic Latex as an Opacifier for Cleansing Formulations ............... 83 Fanwen Zeng, Sylvie Doulut, Miao Wang, Alan Nakatani, Diane Routzahn, and Curtis Schwartz 6. Bifunctional Synthetic Fluid: Polyalphaolefin (PAO) - Diphenylamine ........... 95 Abhimanyu O. Patil and Satish Bodige 7. Next Generation Mildness for Personal Care: Nonpenetrating Polymerized Surfactants for Cleansing Applications ............................................................. 105 Michael J. Fevola, Frank C. Sun, Russel M. Walters, and Joseph J. LiBrizzi 8. Stars and Blocks: Tailoring Polymeric Rheology Modifiers for Aqueous Media by Controlled Free Radical Polymerization .......................................... 125 André Laschewsky, Christoph Herfurth, Anna Miasnikova, Frank Stahlhut, Jan Weiss, Christoph Wieland, Erik Wischerhoff, Michael Gradzielski, and Paula Malo de Molina 9. Biodegradable, Bioactive-Based Poly(anhydride-esters) for Personal Care and Cosmetic Applications .................................................................................. 145 A. L. Carbone-Howell, M. A. Ouimet, and K. E. Uhrich 10. Controlled Synthesis of Multifunctional Polymers by RAFT for Personal Care Applications ................................................................................................. 157 Matthias Haeussler, John Chiefari, Graeme Moad, and Ezio Rizzardo Part 3: Applications 11. Mechanical Characterization of Cosmetic and Viscoelastic Effects of Firming Polymers ................................................................................................. 175 Chung-yi Chiang, Lei Huang, and Naresh Ghatlia 12. Styrene/Acrylates Copolymer as Film Former for Improved Hair Surface Luster .................................................................................................................... 191 Fanwen Zeng, Miao Wang, Jennifer Collin, Alan Nakatani, Michaeleen Pacholski, John Reffner, and Curtis Schwartz 13. Beyond Thickening DS Use of Alkyl Acrylate Crosspolymer in Personal Care Formulations ........................................................................................................ 205 Daphne Benderly and Yelena Zolotarsky 14. Silicone Wettability and Its Significance in Beauty Products .......................... 219 Michael S. Ferritto and Michael J. Owen 15. Hair Care Polymers for Styling and Conditioning ........................................... 233 Osama M. Musa and Michael A. Tallon 16. The Effect of Counterion, Concentration, and Temperature on the Release of Bioavailable Calcium and Phosphate Ions from Ion Permeable Microcapsules for Remineralization .................................................................. 285 Michelle A. Falbo, Matthew Q. Schmidt, Theresa A. Greving, Michael T. Davidson, William A. McHale, Mark A. Latta, and Stephen M. Gross 17. Adsorption/Desorption Processes of pH-Responsive Copolymers on Model Dental Surfaces via QCM and AFM Analysis ................................................... 301 Yan Zong, Yuhong Wei, and Sarah E. Morgan Editors' Biographies .................................................................................................... 319 Indexes Author Index ................................................................................................................ 323 Subject Index ................................................................................................................ 325
Anjali Patil is affiliated with the Revlon Research Center. Michael S. Ferritto is affiliated with Dow Corning Corporation.